ArF Laser Photolytic Deposition and Thermal Modification of an Ultrafine Chlorohydrocarbon

0361345 - ÚCHP 2012 RIV SK eng J - Článek v odborném periodiku
Pola, Josef - Galíková, Anna - Šubrt, Jan - Ouchi, A.
ArF Laser Photolytic Deposition and Thermal Modification of an Ultrafine Chlorohydrocarbon.
Chemical Papers. Roč. 64, č. 5 (2010), s. 625-629. ISSN 0366-6352.
[International Conference of the Slovak Society of Chemical-Engineering /37./. Tatranské Matliare, 24.05.2010-28.05.2010]
Výzkumný záměr: CEZ:AV0Z40720504; CEZ:AV0Z40320502
Klíčová slova: laser-induced photolysis * cis-1,2-dichloroethene * nanostructured chlorohydrocarbon
Kód oboru RIV: CH - Jaderná a kvantová chemie, fotochemie
Impakt faktor: 0.754, rok: 2010

MW ArF laser irradiation of gaseous cis-dichloroethene results in fast decomposition of this compound and in deposition of solid ultrafine Cl- and H-containing carbonaceous powder which is of interest due to its sub-microscopic structure and possible reactive modification of the C-Cl bonds. The product was characterized by electron microscopy, and FTIR and Raman spectra and it was revealed that HCl, H(2), and C/H fragments are lost and graphitic features are adopted upon heating to 700A degrees C.
Trvalý link: http://hdl.handle.net/11104/0006508