Počet záznamů: 1  

Ambient analysis of trace compounds in gaseous media by SIFT-MS

  1. 1. 0359555 - UFCH-W 2012 RIV GB eng J - Článek v odborném periodiku
    Smith, D. - Španěl, Patrik
    Ambient analysis of trace compounds in gaseous media by SIFT-MS.
    Analyst. Roč. 136, č. 10 (2011), s. 2009-2032 ISSN 0003-2654
    Grant CEP: GA ČR GA202/09/0800; GA ČR GA203/09/0256
    Výzkumný záměr: CEZ:AV0Z40400503
    Klíčová slova: ion-flow tube * mass spectrometry * SIFT-MS
    Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
    Impakt faktor: 4.230, rok: 2011

    The topic of ambient gas analysis has been rapidly developed in the last few years with the evolution of the exciting new techniques such as DESI, DART and EESI. The essential feature of all is that analysis of trace gases can be accomplished either in the gas phase or those released from surfaces, crucially avoiding sample collection or modification. In this regard, selected ion flow tube mass spectrometry, SIFT-MS, also performs ambient analyses both accurately and rapidly. In this focused review we describe the underlying ion chemistry underpinning SIFT-MS through a discourse on the reactions of different classes of organic and inorganic molecules with H3O+, NO+ and O-2(+center dot) studied using the SIFT technique. Rate coefficients and ion products of these reactions facilitate absolute SIFT-MS analyses and can also be useful for the interpretation of data obtained by the other ambient analysis methods mentioned above.
    Trvalý link: http://hdl.handle.net/11104/0197326