Heterogenized Homogeneous Catalysts for Fine Chemicals Production

0341534 - ÚCHP 2011 RIV DE eng M - Část monografie knihy
Zsigmond, A. - Notheisz, F. - Klusoň, Petr - Floriš, Tomáš
Chemoselective and Enantioselective Hydrogenations on Immobilized Complexes.
Heterogenized Homogeneous Catalysts for Fine Chemicals Production. Vol. 34. Dordrecht: Springer, 2010 - (Barbaro, P.; Liguori, F.), s. 283-360. ISBN 978-90-481-3695-7
Výzkumný záměr: CEZ:AV0Z40720504
Klíčová slova: Ru-BINAP * hydrogenation * ionic liquids
Kód oboru RIV: CC - Organická chemie
http://www.springerlink.com/content/978-90-481-3695-7#section=759918&page=1&locus=10

Homogeneous catalysts, which are mixed with the reactants at the molecular level, typically show the highest activity and selectivity as they offer chemically well-defined active sites and are not limited by heat and mass transport. However, an inherent disadvantage of the homogeneous catalysis is the need to separate the catalyst from a product after the reaction. Therefore, solid or immobilized homogeneous catalysts are preferred in industry. In this contribution we pay attention to chemoselectivity, regioselectivity and enantio¬selectivity in the synthesis of fine chemicals by means of hydrogenation reactions with immobilised homogeneous complexes.
Trvalý link: http://hdl.handle.net/11104/0184481