Copper(II) acetates with aliphatic/heterocyclic amines - Coupled TG-DTA-EGA study, IR characterization and structure correlation

0339816 - ÚACH 2010 RIV HU eng J - Článek v odborném periodiku
Zeleňák, V. - Vargová, Z. - Györyová, K. - Večerníková, Eva - Balek, V.
Copper(II) acetates with aliphatic/heterocyclic amines - Coupled TG-DTA-EGA study, IR characterization and structure correlation.
Journal of Thermal Analysis and Calorimetry. Roč. 82, - (2005), s. 747-754. ISSN 1388-6150. E-ISSN 1588-2926
Výzkumný záměr: CEZ:AV0Z40320502
Klíčová slova: copper acetate * 1,3-diaminopropane * DTA
Kód oboru RIV: CA - Anorganická chemie
Impakt faktor: 1.425, rok: 2005

Three copper acetate complex compounds, namely Cu(CH3COO)(2)(en)(2)center dot 2H(2)O (I), Cu(CH3COO)(2)(tn)(2)(II) and Cu-2(CH3COO)(4)(pyz) (III) (en=ethylenediamine, tn=1,3-diaminopropane, pyz=pyrazine), were prepared and characterized during heating in argon by thermogravimetry (TG), differential thermal analysis (DTA) and evolved gas analysis (EGA) using mass spectrometry (MS). The results of infrared spectroscopy (IR) were evaluated to be used as a spectroscopic criterion for the determination of the carboxylate binding mode in the compounds.
Trvalý link: http://hdl.handle.net/11104/0183230