Reactions of the dications C7H62+, C7H72+, and C7H82+ with methane: Predominance of doubly charged intermediates

0326568 - ÚOCHB 2010 RIV NL eng J - Článek v odborném periodiku
Roithová, J. - Ricketts, Claire - Schröder, Detlef
Reactions of the dications C7H62+, C7H72+, and C7H82+ with methane: Predominance of doubly charged intermediates.
International Journal of Mass Spectrometry. Roč. 280, 1/3 (2009), s. 32-37. ISSN 1387-3806. E-ISSN 1873-2798
Výzkumný záměr: CEZ:AV0Z40550506
Klíčová slova: bond forming reactions * dications * DFT calculations * electron transfer * hydride transfer
Kód oboru RIV: CC - Organická chemie
Impakt faktor: 2.117, rok: 2009

The reactions of methane with the dications C7H62+, C7H72+, and C7H82+ generated by electron ionization of toluene are studied by mass spectrometry. It is shown that the reactivity is dominated by the formation of doubly charged intermediates.
Trvalý link: http://hdl.handle.net/11104/0173633