Počet záznamů: 1
Synthesis of 3-hexahelicenol and its transformation to 3-hexahelicenylamines, diphenylphosphine, methyl carboxylate, and dimethylthiocarbamate
- 1.0195037 - UOCHB-X 20030345 RIV US eng J - Článek v odborném periodiku
Teplý, Filip - Stará, Irena G. - Starý, Ivo - Kollárovič, Adrian - Šaman, David - Vyskočil, Š. - Fiedler, Pavel
Synthesis of 3-hexahelicenol and its transformation to 3-hexahelicenylamines, diphenylphosphine, methyl carboxylate, and dimethylthiocarbamate.
Journal of Organic Chemistry. Roč. 68, č. 13 (2003), s. 5193-5197. ISSN 0022-3263. E-ISSN 1520-6904
Grant CEP: GA ČR GA203/99/1448; GA ČR GA203/02/0248
Výzkumný záměr: CEZ:AV0Z4055905
Klíčová slova: 3-hexahelicenol * 3-hexahelicenylamines * transformation
Kód oboru RIV: CC - Organická chemie
Impakt faktor: 3.297, rok: 2003
A nonphotochemical synthetic route to 3-hexahelicenol is reported. It involves a key [2+2+2] cycloisomerization of CH3O-substituted triyne that is readily available from 1-methoxy-3-methyl-benzene and 1-bromo-2-(bromomethyl)naphthalene.
Trvalý link: http://hdl.handle.net/11104/0090704
Počet záznamů: 1