0194605 - UOCHB-X 20020276 RIV GB eng J - Článek v odborném periodiku
Teplý, Filip - Stará, Irena G. - Starý, Ivo - Kollárovič, Adrian - Šaman, David - Fiedler, Pavel
Transition metal control in the reaction of alkyne-substituted phenyl iodides with terminal alkynes: Sonogashira coupling vs cyclic carbopalladation.
Tetrahedron. Roč. 58, č. 44 (2002), s. 9007-9018. ISSN 0040-4020. E-ISSN 1464-5416
Grant CEP: GA ČR GA203/99/1448
Výzkumný záměr: CEZ:AV0Z4055905
Klíčová slova: alkynes
Kód oboru RIV: CC - Organická chemie
Impakt faktor: 2.420, rok: 2002

Reaction between terminal alkynes and phenyl iodides bearing a tethered alkyne unit can be effectively controlled by the nature of a transition metal catalyst; the use of Pd(0)/Cu(I) promotes the Sonogashira coupling where as the absence of the copper co-catalyst cyclic carbopalladation.
Trvalý link: http://hdl.handle.net/11104/0090279