0194418 - UOCHB-X 20020084 RIV US eng J - Článek v odborném periodiku
Kasal, Alexander - Buděšínský, Miloš - Drašar, Pavel
Analogues of androgen hormones with inverted configuration at carbons 5, 9, and 10.
Steroids. Roč. 67, - (2002), s. 57-70. ISSN 0039-128X. E-ISSN 1878-5867
Grant CEP: GA ČR GA505/94/0009
Výzkumný záměr: CEZ:AV0Z4055905
Klíčová slova: catalytic hydrogenation
Kód oboru RIV: CC - Organická chemie
Impakt faktor: 2.524, rok: 2002

On catalytic hydrogenation of Westphalen-type steroids, four isomers were formed.The product distribution was affected by the nature of the C-3 substituent. A chair conformation of A, B, and C rings was found in all of the products with the exception of the 9ŕ,10ŕ-adduct whose B ring adopts a twist boat conformation. The products were utilized for the synthesis of dihydrotestosterone.
Trvalý link: http://hdl.handle.net/11104/0090093