Počet záznamů: 1  

(3+3)-Cyclocondensation of the enantiopure and racemic forms of .I.trans./I.-1,2-diaminocyclohexane with terephthaldehyde. Formation of diastereomeric molecular triangles and their stereoselective solid-state stacking into microporous chiral columns

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    0194308 - UOCHB-X 20010153 RIV GB eng J - Článek v odborném periodiku
    Chadim, Martin - Buděšínský, Miloš - Hodačová, Jana - Závada, Jiří - Junk, P. C.
    (3+3)-Cyclocondensation of the enantiopure and racemic forms of .I.trans./I.-1,2-diaminocyclohexane with terephthaldehyde. Formation of diastereomeric molecular triangles and their stereoselective solid-state stacking into microporous chiral columns.
    Tetrahedron Asymmetry. Roč. 12, č. 1 (2001), s. 127-133. ISSN 0957-4166
    Grant CEP: GA ČR GA203/98/0726
    Výzkumný záměr: CEZ:AV0Z4055905
    Klíčová slova: microcycles * amines
    Kód oboru RIV: CC - Organická chemie
    Impakt faktor: 2.265, rok: 2001

    Reaction of both the homochiral as well as the racemic form of .I.trans./I.-1,2-diaminocyclohexane with terephthaldehyde affords (3+3)-cyclocondensed molecular triangles in quantitative yields. Unambiguous proof has been obtained by X-ray crystal structure analysis of both alternative diastereomers, revealing also a stereoselective stacking of the triangles into microporous chiral columns.
    Trvalý link: http://hdl.handle.net/11104/0089990

     
     

Počet záznamů: 1  

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