0193795 - UOCHB-X 20000227 RIV CZ eng J - Článek v odborném periodiku
Alexander, Daniel - Böhm, S. - Císařová, I. - Holý, Petr - Podlaha, J. - Šlouf, M. - Závada, Jiří
Sterically crowded hexaalkyl benzene-1,2,3,4,5,6-hexakis-[ŕ-(alkoxycarbonyl)propanoates]. Synthesis and conformation analysis.
Collection of Czechoslovak Chemical Communications. Roč. 65, č. 5 (2000), s. 673-694. ISSN 0010-0765
Grant CEP: GA ČR GA203/97/0242; GA ČR GA203/97/0025
Výzkumný záměr: CEZ:AV0Z4055905
Kód oboru RIV: CC - Organická chemie
Impakt faktor: 0.960, rok: 2000

A selective hexa-fold monoalkylation of the malonester carbanion -CH(COOR)2 with hexakis(bromomethyl)benzene afforded the title compounds in high-yields. On subsequent replacement of the acid ŕ-hydrogens with bulkier substituents a series of sterically crowded derivatives was prepared for their conformation analyses.
Trvalý link: http://hdl.handle.net/11104/0089487