0181562 - UFCH-W 20020196 RIV US eng J - Článek v odborném periodiku
Mitri, R. - Hartmann, M. - Pittner, Jiří - Bonačič-Koutecký, V.
New Strategy for Optimal Control of Femtosecond Pump-Dump Processes.
Journal of Physical Chemistry A. Roč. 106, č. 7 (2002), s. 10477-10481. ISSN 1089-5639. E-ISSN 1520-5215
Výzkumný záměr: CEZ:AV0Z4040901
Klíčová slova: pump-dump processe * femtosecond * new strategy
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
Impakt faktor: 2.765, rok: 2002

We propose a new strategy for optimal control with tailored pump-dump pulses which drive a system of moderate complexity via electronically excited states to a desired objective in the ground state with a maximal yield. It is based on the concept of the intermediate target in the excited state which selects the appropriate Franck-Condon window at a given time delay between the two pulses mandatory for reaching optimally the objective. The existence of the intermediate target ensures the connective pathway between the initial state and the objective in the ground state, necessary for the controllability of multidimensional systems involving two electronic state.
Trvalý link: http://hdl.handle.net/11104/0001907