0181501 - UFCH-W 20020239 RIV NL eng J - Článek v odborném periodiku
Bulánek, R. - Novoveská, K. - Wichterlová, Blanka
Oxidative Dehydrogenation and Ammoxidation of Ethane and Propane over Pentasil Ring Co-zeolites.
Applied Catalysis A - General. Roč. 235, - (2002), s. 181-191. ISSN 0926-860X. E-ISSN 1873-3875
Grant CEP: GA ČR GA203/99/D073; GA ČR GA104/00/0640
Výzkumný záměr: CEZ:AV0Z4040901
Klíčová slova: ethane * propane * ammoxidation
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
Impakt faktor: 1.915, rok: 2002

The activity of Co-zeolites with MFI, BEA, FER, MOR topologies was studied in ethane and propane oxidative dehydrogenation and ammoxidation in a through-flow arrangement and temperature range 350-500degreesC. The products of oxidative dehydrogenation of paraffins were corresponding olefins, CO and CO2, in the propane reaction only a small part was cracked to ethylene and methane. Besides CO and CO2, the ammoxidation of ethane yielded ethylene and acetonitrile, and of propane brought propylene and acetonitrile too. Presence of ammonia increased substantially the paraffin conversion as well as selectivity and yield of the sum of olefin and nitrile for CoH-BEA and CoH-MFI zeolites, while with CoNa-zeolites the paraffin conversion and selectivity were similar.
Trvalý link: http://hdl.handle.net/11104/0001896