0181407 - UFCH-W 20020072 RIV NL eng J - Článek v odborném periodiku
Španěl, Patrik - Van Doren, J. M. - Smith, D.
Selected Ion Flow Tube Study of the Reactions of H3O+, NO+ and O2+ with Saturated and Unsaturated Aldehydes and Subsequent Hydration of the Product Ions.
International Journal of Mass Spectrometry. Roč. 213, 2/3 (2002), s. 134-144. ISSN 1387-3806. E-ISSN 1873-2798
Grant CEP: GA ČR GA203/00/0632
Výzkumný záměr: CEZ:AV0Z4040901
Klíčová slova: SIFT * proton transfer * hydride ion transfer
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
Impakt faktor: 2.134, rok: 2002

Reactions of H3O+ with the aldehydes result in the protonated molecules and for the saturated aldehydes also in ions resulting from the loss of an H2O molecule from the nascent MH+ ion. No+ reactions invariably proceed via the process of hydride ion transfer, but parallel minor association product ions NO+.M are observed for some of the unsaturated aldehyde reactions. O2+ reactions proceed via charge transfer producing nascent parent ions that partially dissociate producing fragment ions.
Trvalý link: http://hdl.handle.net/11104/0077981