0181377 - UFCH-W 20020037 RIV NL eng J - Článek v odborném periodiku
Kavan, Ladislav - Dunsch, L. - Kataura, H.
In-situ Vis-NIR and Raman Spectroelectrochemistry at Fullerene Peapods.
Chemical Physics Letters. Roč. 361, č. 1 (2002), s. 79-85. ISSN 0009-2614. E-ISSN 1873-4448
Grant CEP: GA MŠMT OC D14.10
Výzkumný záměr: CEZ:AV0Z4040901
Klíčová slova: carbon * Raman spectroscopy * spectroelectrochemistry
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
Impakt faktor: 2.526, rok: 2002

The population of valence-band electronic states of fullerene peapods (C60@SWCNT) was tuned electrochemically in acetonitrile solutions. Electrochemistry of peapods was diminated by their capacite charning without distinct faradaic processes. In situ Vis-NIR spectra of peapods showed similar features as those of empty nanotubes. Electrochemical charning caused reversible bleaching of the transitions between Van Hove singularities. This bleaching was mirrored by quenching of resonance Raman spectra.
Trvalý link: http://hdl.handle.net/11104/0001877