0181309 - UFCH-W 20010232 RIV NL eng C - Konferenční příspěvek (zahraniční konf.)
Drozdová, L. - Marturano, P. - Wichterlová, Blanka - Kogelbauer, A. - Prins, R.
Exafs Study of Fe/ZSM-5 Prepared by Chemical Vapour Deposition and Co/FER, MOR, MFI Prepared by Ion Exchange.
Proceedings of the NATO Advanced Research Workshop on Catalysis by Unique Metal Ion Structures in Solid Matrices. Dordrecht: Kluwer, 2001 - (Centi, G.; Wichterlová, B.; Bell, A.), s. 85-94. NATO Science Series. Mathematics, Physics and Chemistry. 13.
[Workshop on Catalysis by Unique Metal Ion Structures in Solid Matrices. Praha-Průhonice (CZ), 04.07.2000-07.07.2000]
Grant CEP: GA MŠMT OC D15.20
Výzkumný záměr: CEZ:AV0Z4040901
Klíčová slova: Fe/ZSM-5 * FTIR and CO/H2 * Fe model-complexes
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie

The existence of binuclear oxo-iron clusters in Fe/ZSM-5, which was postulated on the basis of FTIR and CO/H2 TPR experiments, was unambiguously confirmed by EXAFS. By comparison with data of Fe model-complexes available in the literature, it is proposed that the Fe species adopt a structure closely resembling the "diamond core" of the methane monooxygenase enzyme (Fe(ć-OH)2Fe).
Trvalý link: http://hdl.handle.net/11104/0077891