0181204 - UFCH-W 20010119 RIV CH eng J - Článek v odborném periodiku
Berger, S. - Hartmann, H. - Wanner, M. - Fiedler, Jan - Kaim, W.
Tetranuclear Complexes {(ć₄-TCNX([Cu(Me₃TACN)]₄}(BF₄)₄ with TCNX=TCNE, TCNQ or TCNB (1,2,4,5-tetracyanobenzene) and Me₃TACN=1,4,7-trimethyl-1,4,7-triazacyclononane.
Inorganica chimica acta. Roč. 314, - (2001), s. 22-26. ISSN 0020-1693. E-ISSN 1873-3255
Grant CEP: GA MŠMT OC D15.10
Výzkumný záměr: CEZ:AV0Z4040901
Klíčová slova: copper compounds * infrared spectra * TCNQ complexes
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
Impakt faktor: 1.394, rok: 2001

The poorly soluble (TCNB) or insoluble compounds (TCNE, TCNQ) exhibit nitrile stretching frequencies compatible with only a moderate metal-to-TCNX electron transfer, in contrast to results obtained for previously reported tetranuclear species from the reaction of TCNX ligands with complex fragments containing d6 metal centers (Mn I, Ru II, Os II). The TCNB complex was characterized in solution by cyclic voltammetry, 1H NMR, IR and UV-Vis spectroelectrochemistry and by EPR of the le reduced form.
Trvalý link: http://hdl.handle.net/11104/0077790