0181129 - UFCH-W 20010036 RIV CZ eng J - Článek v odborném periodiku
Heyrovský, Michael
Electrocatalysis of Hydrogen Evolution by Transition Metal Complexes.
Collection of Czechoslovak Chemical Communications. Roč. 66, č. 1 (2001), s. 67-80. ISSN 0010-0765
Grant CEP: GA ČR GV204/97/K084
Výzkumný záměr: CEZ:AV0Z4040901
Klíčová slova: transition metals * thiocyanate complexes * electroreduction
Kód oboru RIV: CG - Elektrochemie
Impakt faktor: 0.778, rok: 2001

Voltammetric reduction of monothiocyanate complexes of the iron group metals is accompanied by catalytic evolution of hydrogen in two potential regions: around-1.3 V vs SCE, hydrogen is evolved at the surface of the electrodeposited metal, around 1.6 V at the surface of mercury. The catalyst is the protonated, reduced, zero-valent form of the complex which has limited stability.
Trvalý link: http://hdl.handle.net/11104/0077725