1)The authors of the file data are the same as in the publication

2) Data Files

Nature_Comm_figures 3_Photophysical properties of hetero-ligand MOF nanocrystals.TXT	
Nature_Comm_figures 4_ Luminescence properties of MOF-based nanocomposites under X-ray exposure.TXT	
Nature_Comm_figures 5_Scintillation properties of large Stokes shift MOF-based nanocomposites.TXT	
Supplementary Data File 1_Raw data for the Rietveld fits of X-ray data for Zr-DPTDPA-0.x structures.txt	
Supplementary Information_nat-comm.pdf

3)Data files txt and pdf format

4)Nature_Comm_figures 3_Photophysical properties of hetero-ligand MOF nanocrystals.TXT
Photophysical properties of hetero-ligand MOF nanocrystals.
- Normalized absorption and photoluminescence spectra of the hetero-ligand Zr-DPT:DPA-1% nanocrystals in tetrahydrofuran (THF) compared with homo-ligand MOFs based on DPA (ZrDPA, 0.1 mg mL−1) and DPT (Zr-DPT, 0.1 mg mL−1).
- The excitation wavelength is 355 nm. The excitation photoluminescence spectrum of the Zr-DPT:DPA-1% dispersion recorded at 540 nm is included.
- PL spectrum of the Zr-DPT:DPA-1% dispersion at different dilution ratios under 355 laser excitation
- PL intensity decay with time recorded at 430 nm and 540 nm  at the same dilution ratios of Zr-DPT:DPA-1% in comparison with that of Zr-DPA and Zr-DPT.
- Energy transfer efficience between DPA and DPT co-ligands as a function of their relative molar ratio in the MOF framework and fit of experimental data
- Normalized PL spectra of the hetero-ligand nanocrystals dispersions series (0.1 mg mL−1 ) 
- time-resolved PL spectra recorded at 430 nm and the fit of the data with multi-exponential decay function. 
- Absorption and PL spectrum of Zr-DPT:DPA-8% nanocrystals in THF (0.1 mg mL−1, optical path 1 cm). The excitation wavelength is 355 nm.

 Nature_Comm_figures 4_ Luminescence properties of MOF-based nanocomposites under X-ray exposure
- Experimental and simulated radioluminescence spectrum of nanocomposites loaded with hetero-ligand Zr-DPT:DPA-8% and homo-ligand Zr-DPA nanocrystals in polydimethylsiloxane (PDMS) as host polymer matrix (0.5% wt, 1 mm thickness) under X-ray exposure 
- Zr-DPT:DPA-8% nanocomposite photoluminescence intensity decay recorded at 430 nm  and 540 nm as function of the temperature under pulsed laser excitation at 405 nm. 
- RL spectrum of the Zr-DPT:DPA-8% nanocomposite as a function of the temperature. 
- Simulated output emission spectrum and efficiency (β) as a function of the scattering level (from 0 cm−1 to 20 cm−1) in a 10 × 10 × 5 mm scintillator.
- Single molecule emission spectrum of the DPA  and DPT chromophores for reference.

 Nature_Comm_figures 5_Scintillation properties of large Stokes shift MOF-based nanocomposites
- 2D map of the time resolved photoluminescence of the composite under 405 pulse laser excitation. 
- Decays in time of the PL intensity recorded at 540 nm and 450 nm. 
- 2D map of the composite scintillation emission under pulsed X-rays exposure. 
- Decay in time of the scintillation pulse intensity recorded at 540 nm and 450 nm. 
- Scintillation pulse recorded in the ultrafast time scale with the instrumental response function and the fit of the data with a pulse function convoluted with the IRF

5)Licence 
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