Počet záznamů: 1
Zeolite supported palladium catalysts for hydroalkylation of phenolic model compounds
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SYSNO ASEP 0476368 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Zeolite supported palladium catalysts for hydroalkylation of phenolic model compounds Tvůrce(i) Akhmetzyanova, U. (CZ)
Opanasenko, Maksym (UFCH-W) RID, ORCID
Horáček, J. (CZ)
Montanari, E. (IT)
Čejka, Jiří (UFCH-W) RID, ORCID, SAI
Kikhtyanin, O. (CZ)Zdroj.dok. Microporous and Mesoporous Materials. - : Elsevier - ISSN 1387-1811
Roč. 252, NOV 2017 (2017), s. 116-124Poč.str. 9 s. Jazyk dok. eng - angličtina Země vyd. NL - Nizozemsko Klíč. slova Phenol hydroalkylation ; Cyclohexylcyclohexane ; MWW Vědní obor RIV CF - Fyzikální chemie a teoretická chemie Obor OECD Physical chemistry CEP GBP106/12/G015 GA ČR - Grantová agentura ČR Institucionální podpora UFCH-W - RVO:61388955 UT WOS 000407658700012 EID SCOPUS 85020518184 DOI 10.1016/j.micromeso.2017.06.020 Anotace Bifunctional palladium-based catalysts with zeolite supports were investigated in phenol hydroalkylation, representing high-potential model reaction for transformation of lignocellulose-derived compounds to automotive and jet fuels. Conversion of phenol correlated with the amount of accessible acid sites and textural properties of the solid acid support: under the same reaction conditions and at the same Pd loading. The highest phenol conversions (99-100%) were obtained for large-pore zeolite Beta and mesopore-containing MCM-36/56 materials. The selectivity towards the targeted cyclohexylcyclohexane on different supports decreased in the following order Beta (57%) > MCM-36 (42%) approximate to MCM-56 (37%) > MCM-22 (20%), while the contribution of undesired reaction termination through formation of non-reactive cyclohexane was more pronounced for the expanded MCM-36/56 based catalysts. Substrate consumption after 60 min over the least active MCM-22-based catalysts increased with increasing Pd content as follows 27% (0.3 wt % Pd), 80% (0.5 wt % Pd) and 98% (0.7 wt % Pd). High activity of Pd/Beta catalysts was not vitiated even by sintering effects being the most pronounced for Beta as a support. (C) 2017 Elsevier Inc. All rights reserved. Pracoviště Ústav fyzikální chemie J.Heyrovského Kontakt Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Rok sběru 2018
Počet záznamů: 1